Search results for "ISM [galaxies]"
showing 10 items of 699 documents
Carboxylated-xyloglucan and peptide amphiphile co-assembly in wound healing.
2021
Abstract Hydrogel wound dressings can play critical roles in wound healing protecting the wound from trauma or contamination and providing an ideal environment to support the growth of endogenous cells and promote wound closure. This work presents a self-assembling hydrogel dressing that can assist the wound repair process mimicking the hierarchical structure of skin extracellular matrix. To this aim, the co-assembly behaviour of a carboxylated variant of xyloglucan (CXG) with a peptide amphiphile (PA-H3) has been investigated to generate hierarchical constructs with tuneable molecular composition, structure, and properties. Transmission electron microscopy and circular dichroism at a low c…
Chiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands
2019
Two constitutionally isomeric chiral bis(pyridine) ligands based on planar chiral 4,15-difunctionalized [2.2]paracyclophanes were synthesized, the respective enantiomers were separated via HPLC on a chiral stationary phase, and their self-assembly behaviour upon coordination to palladium(ii) ions was studied with regard to chiral self-sorting effects. As proven by NMR spectroscopy, mass spectrometry, CD spectroscopy, UV-Vis spectroscopy and X-ray crystallography both ligands form the expected dinuclear complexes upon coordination to cis-protected di- or tetravalent palladium(ii) ions, respectively, however, with distinct differences concerning their chiral self-sorting ability. peerReviewed
Formation of a novel ferromagnetic end-to-end cyanate bridged homochiral helical copper(ii) Schiff base complex via spontaneous symmetry breaking
2014
A homochiral helical coordination polymer of copper(II) has been synthesized using achiral precursors via spontaneous symmetry breaking and has been confirmed by single crystal X-ray diffraction and solid-state CD spectroscopy. The variable temperature magnetic measurements indicate the presence of weak ferromagnetic exchange interactions mediated by end-to-end cyanate bridges (J = +0.12 cm(-1)).
Assessing the impact of copy number variants on miRNA genes in autism by Monte Carlo simulation.
2014
Autism Spectrum Disorders (ASDs) are childhood neurodevelopmental disorders with complex genetic origins. Previous studies have investigated the role of de novo Copy Number Variants (CNVs) and microRNAs as important but distinct etiological factors in ASD. We developed a novel computational procedure to assess the potential pathogenic role of microRNA genes overlapping de novo CNVs in ASD patients. Here we show that for chromosomes # 1, 2 and 22 the actual number of miRNA loci affected by de novo CNVs in patients was found significantly higher than that estimated by Monte Carlo simulation of random CNV events. Out of 24 miRNA genes over-represented in CNVs from these three chromosomes only …
How does the brain encode epistemic reliability? Perceptual presence, phenomenal transparency, and counterfactual richness
2014
AbstractSeth develops a convincing and detailed internalist alternative to the sensorimotor-contingency theory of perceptual phenomenology. However, there are remaining conceptual problems due to a semantic ambiguity in the notion of “presence” and the idea of “subjective veridicality.” The current model should be integrated with the earlier idea that experiential “realness” and “mind-independence” are determined by the unavailability of earlier processing stages to attention. Counterfactual richness and attentional unavailability may both be indicators of the overall processing level currently achieved, a functional property that normally correlates with epistemic reliability. Perceptual p…
On the automorphism group of the integral group ring of Sk wr Sn
1992
Abstract Let G = SkwrSn be the wreath product of two symmetric groups Sk and Sn. We prove that every normalized automorphism θ of the integral group ring Z G can be written in the form θ = γ ° τu, where γ is an automorphism of G and τu denotes the inner automorphism induced by a unit u in Q G.
Automorphisms of the integral group ring of the hyperoctahedral group
1990
The purpose of this paper is to verify a conjecture of Zassenhaus [3] for hyperoctahedral groups by proving that every normalized automorphism () of ZG can be written in the form () = Tu 0 I where I is an automorphism of ZG obtained by extending an automorphism of G linearly to ZG and u is a unit of (JJG. A similar result was proved for symmetric groups by Peterson in [2]; the reader should consult [3] or the survey [4] for other results of this kind. 1989
Characterization of chain geometries of finite dimension by their automorphism group
1990
A large class of chain geometries of finite dimension is characterized as strong chain spaces possessing a distinguished group of automorphisms fixing two distant points.
Divisible Designs Admitting, as an Automorphism Group, an Orthogonal Group or a Unitary Group
2001
We construct some divisible designs starting from a projective space. These divisible designs admit an orthogonal group or a unitary group as an automorphism group.